| 1 |  Leonardo Bertagnolli (ITA) | Liquigas | 5.12.42 |
| 2 |  Juan Manuel Gárate Cepa (SPA) | Quick Step - Innergetic | s.t. |
| 3 | Alejandro Valverde Belmonte (SPA) | Caisse d'Epargne | 0.18 |
| 4 | Alessandro Ballan (ITA) | Lampre - Fondital | s.t. |
| 5 | Carlos Barredo Llamazales (SPA) | Quick Step - Innergetic | s.t. |
| 6 | Mikel Astarloza Chaurreau (SPA) | Euskaltel - Euskadi | s.t. |
| 7 | Carlos Sastre Candil (SPA) | Team CSC | s.t. |
| 8 | Inigo Landaluze Intxaurraga (SPA) | Euskaltel - Euskadi | 0.28 |
| 9 | Xavier Florencio Cabre (SPA) | Bouygues Télécom | s.t. |
| 10 | Giovanni Visconti (ITA) | Quick Step - Innergetic | 0.37 |
| 11 | Davide Rebellin (ITA) | Gerolsteiner | s.t. |
| 12 | Matteo Carrara (ITA) | Unibet.com | s.t. |
| 13 |  Robert Gesink (NED) | Rabobank | s.t. |
| 14 | Juan Jose Cobo Acebo (SPA) | Saunier Duval - Prodir | s.t. |
| 15 |  Christian Vandevelde (USA) | Team CSC | s.t. |
| 16 | Manuel Beltran Martinez (SPA) | Liquigas | s.t. |
| 17 | Jose Luis Arrieta Lujambio (SPA) | AG2R Prévoyance | s.t. |
| 18 | Gorka Verdugo Marcotegui (SPA) | Euskaltel - Euskadi | s.t. |
| 19 | José Miguel Elías Galindo (SPA) | Relax Colchon - Fuenlabrada | s.t. |
| 20 | Jesús Hernández Blázquez (SPA) | Relax - Gam | s.t. |
| 21 |  Michael Albasini (SWI) | Liquigas | s.t. |
| 22 | José Ángel Gómez Marchante (SPA) | Saunier Duval - Prodir | 0.39 |
| 23 | Haimar Zubeldia Aguirre (SPA) | Euskaltel - Euskadi | 0.41 |
| 24 |  Jurgen Van De Walle (BEL) | Quick Step - Innergetic | 0.43 |
| 25 | Bram Tankink (NED) | Quick Step - Innergetic | 1.36 |
| 26 |  Fränk Schleck (LUX) | Team CSC | s.t. |
| 27 |  Rigoberto Uran Uran (COL) | Unibet.com | s.t. |
| 28 |  Gustav Erik Larsson (SWE) | Unibet.com | 3.41 |
| 29 | Manuele Mori (ITA) | Saunier Duval - Prodir | 3.54 |
| 30 | Francisco Javier 'Patxi' Vila Errandonea (SPA) | Lampre - Fondital | s.t. |
| 31 |  Andriy Grivko (UKR) | Team Milram | 4.51 |
| 32 | Beat Zberg (SWI) | Gerolsteiner | 5.25 |
| 33 | José Joaquin Rojas Gil (SPA) | Caisse d'Epargne | s.t. |
| 34 | Dries Devenyns (BEL) | Predictor-Lotto | s.t. |
| 35 | Rinaldo Nocentini (ITA) | AG2R Prévoyance | s.t. |
| 36 |  Allan Davis (AUS) | Discovery Channel Pro Cycling Team | s.t. |
| 37 | Alessandro Spezialetti (ITA) | Liquigas | s.t. |
| 38 | Christophe Brandt (BEL) | Predictor-Lotto | s.t. |
| 39 | Mirko Celestino (ITA) | Team Milram | s.t. |
| 40 |  Kjell Carlström (FIN) | Liquigas | s.t. |
| 41 | Aitor Perez Arrieta (SPA) | Caisse d'Epargne | s.t. |
| 42 |  Anthony Charteau (FRA) | Crédit Agricole | s.t. |
| 43 | William Walker (AUS) | Rabobank | s.t. |
| 44 |  Alexandre Botcharov (RUS) | Crédit Agricole | s.t. |
| 45 | Pietro Caucchioli (ITA) | Crédit Agricole | s.t. |
| 46 |  Matej Jurco (SVK) | Team Milram | s.t. |
| 47 | Jose Ramon Troncoso Sobrino (SPA) | Karpin - Galicia | s.t. |
| 48 | Wim Van Huffel (BEL) | Predictor-Lotto | s.t. |
| 49 | Carl Naibo (FRA) | AG2R Prévoyance | s.t. |
| 50 | Paolo Bossoni (ITA) | Lampre - Fondital | s.t. |
| 51 | Sébastien Minard (FRA) | Cofidis | s.t. |
| 52 | Damiano Cunego (ITA) | Lampre - Fondital | s.t. |
| 53 | David Herrero Llorente (SPA) | Karpin - Galicia | s.t. |
| 54 | Juan Antonio Flecha Giannoni (SPA) | Rabobank | s.t. |
| 55 | Joaquim Rodríguez Oliver (SPA) | Caisse d'Epargne | s.t. |
| 56 | Riccardo Ricco (ITA) | Saunier Duval - Prodir | s.t. |
| 57 | David Belda Garcia (SPA) | Fuerteventura - Canarias | s.t. |
| 58 | Volodymir Gustov (UKR) | Team CSC | s.t. |
| 59 | Theo Eltink (NED) | Rabobank | s.t. |
| 60 | Koos Moerenhout (NED) | Rabobank | s.t. |
| 61 |  Janez Brajkovic (SLO) | Discovery Channel Pro Cycling Team | s.t. |
| 62 | Laurens Ten Dam (NED) | Unibet.com | s.t. |
| 63 |  René Mandri (EST) | AG2R Prévoyance | 8.46 |
| 64 |  Matthias Russ (GER) | Gerolsteiner | 10.34 |
| 65 | Matthew Lloyd (AUS) | Predictor-Lotto | s.t. |
